CeO2 nanocubes-graphene oxide as durable and highly active catalyst support for proton exchange membrane fuel cell
نویسندگان
چکیده
Rapid degradation of cell performance still remains a significant challenge for proton exchange membrane fuel cell (PEMFC). In this work, we develop novel CeO2 nanocubes-graphene oxide nanocomposites as durable and highly active catalyst support for proton exchange membrane fuel cell. We show that the use of CeO2 as the radical scavenger in the catalysts remarkably improves the durability of the catalyst. The catalytic activity retention of Pt-graphene oxide-8 wt.% CeO2 nanocomposites reaches as high as 69% after 5000 CV-cycles at a high voltage range of 0.8-1.23 V, in contrast to 19% for that of the Pt-graphene oxide composites. The excellent durability of the Pt-CeO2 nanocubes-graphene oxide catalyst is attributed to the free radical scavenging activity of CeO2, which significantly slows down the chemical degradation of Nafion binder in catalytic layers, and then alleviates the decay of Pt catalysts, resulting in the excellent cycle life of Pt-CeO2-graphene oxide nanocomposite catalysts. Additionally, the performance of single cell assembled with Nafion 211 membrane and Pt-CeO2-graphene oxide catalysts with different CeO2 contents in the cathode as well as the Pt-C catalysts in the anode are also recorded and discussed in this study.
منابع مشابه
Electrodeposition of platinum nanoparticles on reduced graphene oxide as an efficient catalyst for oxygen reduction reaction
Reduced graphene oxide film was synthesized on a glassy carbon electrode by electro reduction of graphene oxide powders in aqueous solution. Then platinum nano particles were deposited on reduced graphene oxide film that was deposited on the glassy carbon electrode via electro reduction of platinum salt. The Physical morphology of the platinum on reduced graphene oxide film was evaluated by sca...
متن کاملElectrochemical Study of Hydrogen Adsorption/Reduction (HAR) Reaction on Graphene Oxide as Electrocatalyst for Proton Exchange Membrane Fuel Cells
In the current work, graphene oxide (GO) samples were prepared at room temperature from graphite flakes using a modified Hummer's method to produce metal-free electrocatalysts. The effect of the duration of the oxidation process on the structural, chemical and physical characteristics of the GO samples was evaluated using X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), ...
متن کاملHigh Pt Loading on Polydopamine Functionalized Graphene as a High Performance Cathode Electrocatalyst for Proton Exchange Membrane Fuel Cells
Morphology and size of platinum nanoparticles are a crucial factor in improving their catalytic activity and stability. Here, we firstly report the synthesis of high loading Pt nanoparticles on polydopamine reduced Graphene. The loading concentration of Pt (nanoparticles) NPs on Graphene can be adjusted in the range of 60-70%.With the insertion of polydopamine between Graphene oxide sheets, sta...
متن کاملThree Dimensional Computational Fluid Dynamics Analysis of a Proton Exchange Membrane Fuel Cell
A full three-dimensional, single phase computational fluid dynamics model of a proton exchange membrane fuel cell (PEMFC) with both the gas distribution flow channels and the Membrane Electrode Assembly (MEA) has been developed. A single set of conservation equations which are valid for the flow channels, gas-diffusion electrodes, catalyst layers, and the membrane region are developed and numer...
متن کاملDynamic investigation of hydrocarbon proton exchange membrane Fuel Cell
Sulfonated polyether ether ketone (SPEEK) is categorized in a nonfluorinated aromatic hydrocarbon proton exchange membrane (PEM) group and considered as a suitable substitute for common per-fluorinated membranes, such as Nafion, due to wider operating temperature, less feed gas crossover, and lower cost. Since modeling results in a better understanding of a phenomenon, in this study a dynamic o...
متن کامل